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Alquimia is an interface that exposes the capabilities of mature geochemistry codes such as [CrunchFlow](http://www.csteefel.com/CrunchFlowIntroduction.html) and [PFLOTRAN](https://bitbucket.org/pflotran/pflotran-dev).

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"Alquimia Copyright (c) 2013-2015, The Regents of the University of California, through Lawrence Berkeley National Laboratory (subject to receipt of any required approvals from the U.S. Dept. of Energy). All rights reserved.

If you have questions about your rights to use or distribute this software, please contact Berkeley Lab's Technology Transfer and Intellectual Property Management at [email protected] referring to "Alquimia (LBNL Ref. 2013-119)."

NOTICE. This software was developed under funding from the U.S. Department of Energy. As such, the U.S. Government has been granted for itself and others acting on its behalf a paid-up, nonexclusive, irrevocable, worldwide license in the Software to reproduce, prepare derivative works, and perform publicly and display publicly. Beginning five (5) years after the date permission to assert copyright is obtained from the U.S. Department of Energy, and subject to any subsequent five (5) year renewals, the U.S. Government is granted for itself and others acting on its behalf a paid-up, nonexclusive, irrevocable, worldwide license in the Software to reproduce, prepare derivative works, distribute copies to the public, perform publicly and display publicly, and to permit others to do so.

Description

Alquimia is a biogeochemistry API and wrapper library, originally developed as part of the DOE ASCEM project, and is an interoperable component of the Department of Energy's [IDEAS](https://ideas-productivity.org/) software productivity project.

The aim is to provide a unified interface to existing "geochemistry engines" such as [CrunchFlow](http://www.csteefel.com/CrunchFlowIntroduction.html) or [PFLOTRAN](https://bitbucket.org/pflotran/pflotran-dev), allowing subsurface flow and transport simulators to access a range of functionality.

It is not an implementation of a biogeochemistry reaction library, and does not do any geochemical calculations.

Building

You'll need working C and Fortran compilers and CMake installed on your system. For UNIX and UNIX-like operating systems, you'll need GNU Make or another capable version of Make installed as well. To build on Windows, you'll need some recent version of Visual Studio and a decent Fortran compiler such as Intel's.

Both engines require PETSc to be installed, with the PETSC_DIR and PETSC_ARCH environment variables set properly. Currently, PETSc must be configured to use 32-bit indices.

PFlotran engine

Currently, Alquimia only works with a particular version of PFlotran: hash 611092f80ddb from the pflotran-dev repository. You can download this revision directly as a ZIP file from https://bitbucket.org/pflotran/pflotran-dev/get/611092f80ddb.zip

NOTE ABOUT BUILDING WITH PETSC 3.6 or later: This version of PFlotran was written to use PETSC 3.5.x, which is slightly different from the later minor releases of PETSc. If you use a later version of PETSc, please note the following:

1. You must create the following symbolic links within $PETSC_DIR:

ln -s $PETSC_DIR/lib/petsc/conf $PETSC_DIR/conf

ln -s $PETSC_DIR/include/petsc/finclude $PETSC_DIR/include/finclude

2. You will see a linking error (for a missing symbol _petsclogbegin_) when building the pflotran_rxn executable. This doesn't prevent libpflotran_rxn.a from being built, nor does it prevent Alquimia from working properly with PFlotran.

The instructions below assume that you are on a UNIX or UNIX-like system, and you have set the environment variable PFLOTRAN_DIR to the top of your PFlotran source directory.

cd $PFLOTRAN_DIR/src/pflotran
make pflotran_rxn

To build PFlotran on Windows, see the instructions [here](https://bitbucket.org/pflotran/pflotran-dev/wiki/Installation/Windows_with_Visual_Studio).

CrunchFlow engine

The CrunchFlow geochemistry engine is located in a special "alquimia" branch of the crunchtope repository on bitbucket. Currently, you need to be a collaborator to access this repository, but steps are being taken to release an open-source version.

When you have the alquimia branch of the repository located at $CRUNCHFLOW_DIR, you can build the geochemistry reaction library by typing

cd $CRUNCHFLOW_DIR
make libcrunchchem.a

At this time, building CrunchFlow's geochemistry engine on Windows is not supported.

Alquimia interface

When you have built all the desired chemistry engines, you can build the Alquimia interface. On UNIX and UNIX-like systems, you can use the following command, which assumes you have set ALQUIMIA_DIR to the top of your Alquimia source tree. Note that you will need to create a build tree from which to invoke CMake.

cd $ALQUIMIA_DIR
mkdir build ; cd build
cmake .. \
  -DCMAKE_C_COMPILER=<C compiler> \
  -DCMAKE_CXX_COMPILER=<C++ compiler> \
  -DCMAKE_Fortran_COMPILER=<Fortran compiler> \
  -DXSDK_WITH_PFLOTRAN=ON \
  -DTPL_PFLOTRAN_LIBRARIES=$PFLOTRAN_DIR/src/pflotran/libpflotranchem.a \
  -DTPL_PFLOTRAN_INCLUDE_DIRS=$PFLOTRAN_DIR/src/pflotran \
  -DXSDK_WITH_CRUNCHFLOW=ON \
  -DTPL_CRUNCHFLOW_LIBRARIES=$CRUNCHFLOW_DIR/libcrunchchem.a \
  -DTPL_CRUNCHFLOW_INCLUDE_DIRS=$CRUNCHFLOW_DIR
make

NOTE: you can omit either of the engines if you aren't building them both. If you don't specify any chemistry engine, Alquimia will halt and remind you that building it without an engine is pointless. So, for example, to build Alquimia with an install of PFlotran at $PFLOTRAN_DIR using MPI compilers, in Debug mode:

cd $ALQUIMIA_DIR
mkdir build ; cd build
cmake .. \
  -DCMAKE_C_COMPILER=`which mpicc` \
  -DCMAKE_CXX_COMPILER=`which mpicxx` \
  -DCMAKE_Fortran_COMPILER=`which mpif90` \
  -DCMAKE_BUILD_TYPE=Debug \
  -DXSDK_WITH_PFLOTRAN=ON \
  -DTPL_PFLOTRAN_LIBRARIES=$PFLOTRAN_DIR/src/pflotran/libpflotranchem.a \
  -DTPL_PFLOTRAN_INCLUDE_DIRS=$PFLOTRAN_DIR/src/pflotran
make

Windows instructions go here.

Testing

To run Alquimia's suite of tests from your build directory, just type

make test

See the CMakeLists.txt file for other available build options, including optimization level, shared/static libraries, build prefix, etc. Alquimia supports all xSDK-compliant build options, which can be passed to CMake when configuring your build.

About

Alquimia is an interface that exposes the capabilities of mature geochemistry codes such as [CrunchFlow](http://www.csteefel.com/CrunchFlowIntroduction.html) and [PFLOTRAN](https://bitbucket.org/pflotran/pflotran-dev).

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